Generating Metastable Isotopes of Short Half-Life in the Home Lab >Tutorial by Geo
"METASTABLE" -"m", small case
m, when appended to an isotope name, means metastable. An isotope that is in a
metastable state has pent up energy inside that WILL be released at some time,
but all normal quantum transitions are forbidden. This energy comes
about from normal nuclear decay of the metastable isotope's parent atom. Usually
when an atom decays, there is an immediate rearrangement of the energy levels
quite quickly in the daughter. So much so, that we often think of the Gamma ray
that is released as part of the decay. It is not. Radioactive decay involves the
transformation of the nucleus in terms of physical particles, into a new
nuclide. Gamma radiation usually comes from the nucleus of the daughter nuclide
as it rebalances its own energy to a ground state or more stable state.
In
some instances, the new atom holds the energy for a finite period of time,
sometimes microseconds, sometime hours. This final release of energy is called
Isometric Transition (abbrev. IT), and allows the nucleus to fall to the stable
state or nearer to a stable state. Thus, Ba-137m has the same weight, number of
nucleons etc. as stable Ba-137. Ditto Tc-99m > Tc-99m, although they have
vastly different properties as far as radiation and half-life.
IsoMERs are two or more nuclides that have same atomic and mass
numbers, but differing in other properties. IsoTOPES have the same
atomic numbers, but different atomic weights and energy ( different number of
Neutrons), while IsoTONES are nuclides with the same number of
Neutrons, but different numbers of Protons.
Sometimes the
Gamma process involves the released photon smacking into an inner shell
electron, disappearing but imparting its energy to the electron, which takes off
from the atom- these are the IC or INTERNAL CONVERSION electrons. This void is
filled from another shell, and that process alone creates a characteristic X-ray
photon, whose energy is equal to the difference of the two electron's binding
energy. If the excitation energy to the escaping electron comes from the atomic
region rather than the nucleus, it is called an Auger Electron.
If a
photon comes from the nucleus, it is called Gamma, if it comes from outside the
nucleus, it is called an X-ray. The origin is the ONLY difference. Likewise,
electrons, be they regular ones or antiparticle positrons, that come from the
nucleus are called Betas. If they come from outside the nucleus ( shell area, or
atomic area) they are called electrons. These is some disagreement among
scientists about calling EC a Beta decay, since the electron goes into the
nucleus, not out of it. Even the folks at Oak Ridge who make my Fe-55 disagree
about this.
Pa-234m Generator



The Spectrum
Techniques Ba-137m generator is nice, and
affordable.
The generator contains 10uCi. of Cs-137 and can produce up to 1000 small aliquots of the short lived Ba-137m isotope with a half-life of 2.6 minutes.

http://www.qsl.net/k0ff/Ba137M.jpg/isogen.jpg
The parent isotope Cs-137 with a half-life of 30.1 years beta decays (94.6%) to the metastable state of Ba-137m. This further decays by gamma emission (662 keV) with a half-life of 2.6 min. to the stable Ba-137 element. During elution using a solution of0.9% NaCl,, the Ba-137m is selectively "milked" from the generator leaving behind the Cs-137 parent. Regeneration of the Ba-137m occurs as the Cs-137 continues to decay, re-establishing equilibrium in less than 1 hour.

http://www.qsl.net/k0ff/Ba137M.jpg/elute.jpg
Those short half life isotopes are fun to chart. It is quite true that Cs-137 is actually a pure beta emitter, but is always found in the presence of the progeny Ba-137m, which gives the typical gamma signature we look for in spectrum analysis.
http://www.qsl.net/k0ff/Ba137M.jpg/Cs-137%20with%20NO%20filter-%20See%2032%20keV-.jpg
Only a few isotopes are truly
gamma free beta minus emitters, H3, C-14, Ni-63 Tc-99, Tl-204, Pm-147 Sr-90/Y-90
and P-32 being the most common. Any time betas are flying about, X-rays are also
being created by them. These can be bremsstrahlung or of the "characteristic"
type, so there is always a lot of "noise" on the scan. Setting up a NaI(Tl)
probe for spectrum analysis includes adding a beta shield to the source holder
for this reason.
We have a small group of spectrum analysis enthusiasts
at:
http://groups.yahoo.com/group/GammaSpectrometry/
Scan details:
Setup:
3M3 3" x 3"
Nai(Tl), Canberra 2007P base, Canberra 727 lead shield-graded to copper. USC-20
set as MCS= Multi Channel Scaler mode, HP laptop
Note: after 7 half lives of any isotope, 99.2% of the
original activity is lost.
George Dowell
New London Nucleonics Laboratory
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